S4J38A FeNiCoCu sealing alloy delivers precisely controlled CTE for ceramic-to-metal and glass sealing. Ideal for hermetic packages, semiconductor devices, aerospace, and medical electronics. MTC EN 10204 3.1 available.

S4J38A Fe-Ni-Co-Cu Controlled Expansion Sealing Alloy
S4J38A controlled expansion sealing alloy is a specialized Fe-Ni-Co-Cu alloy designed for applications requiring controlled thermal expansion and reliable metal-to-glass or metal-to-ceramic sealing.
The alloy is intended for precision sealing structures where thermal expansion compatibility between the metal and the sealing material is critical. Typical application areas include ceramic-to-metal sealing, glass-to-metal sealing, hermetic electronic packaging, semiconductor components, aerospace electronics and medical electronic devices.
Hefei Ke Ningman New Energy Materials Technology Co., Ltd. supplies S4J38A sealing alloy according to application requirements, product dimensions, material specifications and customer drawings.
Material designation note: S4J38A should be specified according to the applicable manufacturer or customer specification. It should not automatically be treated as equivalent to the standardized 4J38 low-expansion machinable alloy unless such equivalence has been verified by technical documentation.
| Property | S4J38A |
|---|---|
| Product designation | S4J38A Sealing Alloy |
| Alloy family | Controlled expansion sealing alloy |
| Alloy system | Fe-Ni-Co-Cu |
| Primary function | Thermal expansion matching |
| Sealing applications | Glass-to-metal and ceramic-to-metal sealing |
| Typical application areas | Hermetic electronics, semiconductor, aerospace and medical electronics |
| Product forms | Customized according to requirements |
| Surface condition | Available according to specification |
| Dimensions | Customized |
| Material documentation | Available according to order requirements |
| Inspection | According to agreed specification |
Chemical composition, CTE and other physical properties should be confirmed against the applicable S4J38A technical specification or material certificate.
What Is S4J38A Sealing Alloy?
S4J38A is a Fe-Ni-Co-Cu controlled expansion sealing alloy developed for precision applications where the thermal expansion behavior of a metallic component must be compatible with glass or ceramic materials.
In a hermetic sealing assembly, the metal and glass or ceramic experience dimensional changes during heating and cooling.
The basic engineering relationship is:
Metal CTE ↔ Glass / Ceramic CTE ↔ Sealing Temperature ↔ Cooling Process
If the thermal expansion mismatch is too large, excessive residual stress can develop at the sealing interface.
This can result in:
Glass cracking
Ceramic cracking
Interface separation
Leakage
Loss of hermeticity
Dimensional deformation
Reduced thermal-cycle reliability
For this reason, S4J38A should be selected according to the actual glass or ceramic material, sealing temperature and component geometry.
Why Use a Controlled Expansion Sealing Alloy?
Controlled expansion alloys are used when ordinary steel or conventional stainless steel cannot provide the required thermal expansion compatibility.
The main advantages of a properly selected controlled expansion sealing alloy include:
Controlled Thermal Expansion
The alloy is engineered to provide predictable dimensional change over the required temperature range.
Improved Sealing Compatibility
A suitable thermal expansion relationship between the metal and glass or ceramic can help reduce residual stress at the sealing interface.
Hermetic Packaging Potential
Controlled expansion alloys are widely used in engineering designs where reliable gas-tight or moisture-resistant sealing is required.
Dimensional Stability
Controlled thermal expansion is particularly important in precision electronic and semiconductor components that experience repeated thermal cycles.
Application Flexibility
Depending on the final material specification, product geometry and sealing process, S4J38A can be evaluated for both glass and ceramic sealing applications.
S4J38A Thermal Expansion and CTE
The coefficient of thermal expansion (CTE) is one of the most important parameters when selecting a sealing alloy.
For S4J38A, the required CTE should be specified according to the customer's actual application rather than relying on a single nominal value.
Important parameters include:
CTE over the required temperature range
Glass or ceramic CTE
Sealing temperature
Operating temperature
Heating rate
Cooling rate
Thermal cycling conditions
Material heat-treatment condition
A typical material-selection process is:
S4J38A CTE → Sealing Material CTE → Thermal Expansion Curve → Sealing Temperature → Thermal Stress Evaluation
For critical applications, customers should provide the target CTE range and temperature interval.
We can then evaluate the required material specification and testing requirements.
S4J38A for Ceramic-to-Metal Sealing
Ceramic-to-metal sealing is commonly used where high electrical insulation, temperature resistance and hermeticity are required.
A controlled expansion alloy can help reduce the thermal mismatch between the metallic component and ceramic material during thermal processing.
Potential applications include:
Ceramic feedthroughs
Hermetic electrical connectors
Semiconductor packages
Ceramic electronic packages
High-reliability terminals
Aerospace electronic components
Medical electronic components
The final alloy selection should consider the exact ceramic grade.
Common engineering parameters include:
Ceramic composition
Ceramic CTE
Sealing temperature
Metallization system
Metal thickness
Joint geometry
Operating temperature
Thermal cycling requirements
S4J38A for Glass-to-Metal Sealing
Glass-to-metal sealing requires careful matching of the thermal expansion characteristics of the glass and metal.
S4J38A can be evaluated for glass sealing applications where a controlled-expansion Fe-Ni-Co-Cu alloy is required.
The sealing process may involve:
Metal Preparation → Cleaning → Surface Conditioning → Glass Assembly → Heating → Sealing → Controlled Cooling → Leak Testing
Important process parameters may include:
Glass composition
Glass CTE
Glass transition temperature
Softening temperature
Sealing temperature
Metal surface condition
Atmosphere
Heating rate
Cooling rate
Joint geometry
The alloy should therefore be selected together with the actual glass rather than selected solely according to the alloy name.
S4J38A for Hermetic Electronic Packaging
Hermetic electronic packaging requires reliable protection against moisture, gases and environmental contamination.
Controlled expansion sealing alloys can be used in metal-to-glass or metal-to-ceramic interfaces within hermetic packages.
Potential applications include:
Semiconductor packages
Electronic housings
Hermetic connectors
Electrical feedthroughs
Sensor packages
Microwave packages
High-reliability electronic components
The selection of S4J38A should be based on the complete package design and sealing material.
S4J38A for Semiconductor Applications
Semiconductor packages often combine metals, ceramics, glass and other materials with different thermal expansion characteristics.
During manufacturing and operation, these materials can experience repeated temperature changes.
A suitable controlled expansion alloy can help engineers manage thermal mismatch at critical interfaces.
Potential applications include:
Semiconductor hermetic packages
Ceramic semiconductor packages
Electrical feedthroughs
Sealed terminals
High-reliability electronic housings
Sensor packages
For semiconductor applications, customers should provide the ceramic or glass grade, target CTE, operating temperature and required package geometry.
S4J38A for Aerospace Electronics
Aerospace electronic components may experience:
Large temperature changes
Thermal cycling
Vibration
Pressure variations
Long service periods
Strict reliability requirements
For these applications, the sealing alloy must be evaluated together with the glass or ceramic sealing material and the complete component design.
S4J38A can be considered for selected aerospace electronic sealing structures where controlled expansion is required.
S4J38A for Medical Electronics
Hermetically sealed medical electronic components require reliable protection of internal electronics from the external environment.
Potential applications include:
Hermetic medical electronic packages
Sensor housings
Electrical feedthroughs
Implantable-device components
Precision medical electronics
Material selection should consider:
Biocompatibility requirements where applicable
Hermeticity
Thermal cycling
Corrosion environment
Sealing material
Component geometry
Regulatory requirements
The final material specification should be agreed according to the actual application.
S4J38A Product Forms
Depending on the required dimensions and production process, S4J38A may be supplied in customized forms such as:
Sheet
Strip
Wire
Rod
Bar
Tube
Foil
Precision-cut material
Stamped components
Customized sealing components
Available dimensions depend on the production route and customer specification.
For precision applications, customers should provide:
Thickness
Width
Diameter
Length
Tolerance
Surface condition
Heat-treatment condition
Quantity
Drawing
S4J38A Manufacturing Process
Precision controlled-expansion alloys require careful control of both chemical composition and processing condition.
A typical manufacturing route may include:
1. Raw Material Selection
Raw materials are selected according to the required Fe-Ni-Co-Cu alloy specification.
2. Melting and Alloying
Controlled melting is used to achieve the required chemical composition and material uniformity.
3. Homogenization
Thermal processing can be used to improve compositional and microstructural uniformity.
4. Hot Working
The alloy is processed into an intermediate form suitable for further manufacturing.
5. Cold Working
Rolling, drawing or other precision processes are used to achieve the required dimensions.
6. Intermediate Annealing
Annealing may be applied to control hardness, residual stress and workability.
7. Final Heat Treatment
The final material condition is controlled according to the required thermal expansion and application specification.
8. Surface Finishing
Surface treatment may include cleaning, grinding, polishing or other finishing processes according to the application.
9. Final Inspection
The finished product can be inspected for:
Chemical composition
Dimensions
Surface quality
Mechanical properties
Thermal expansion characteristics
Product condition
Material traceability
S4J38A Quality Control
For hermetic sealing applications, material consistency is critical.
Our quality-control program can include:
Chemical Composition Testing
Chemical composition can be verified according to the agreed S4J38A specification.
Dimensional Inspection
Inspection may cover:
Thickness
Width
Diameter
Length
Flatness
Straightness
Dimensional tolerance
Surface Inspection
Surface inspection can identify:
Cracks
Scratches
Pitting
Scale
Oxidation
Laminations
Other visible defects
Thermal Expansion Testing
CTE testing can be performed over the temperature range specified by the customer.
The test temperature range should be clearly defined because CTE is temperature-dependent.
Mechanical Testing
Where required, testing may include:
Tensile strength
Elongation
Yield strength
Hardness
Material Traceability
Production batches can be linked to inspection records and material documentation according to order requirements.
S4J38A vs Other Controlled Expansion Sealing Alloys
Different sealing alloys are designed for different glass or ceramic systems.
| Alloy Family | Main Alloy System | Typical Application Direction |
|---|---|---|
| S4J38A | Fe-Ni-Co-Cu | Controlled expansion glass/ceramic sealing |
| 4J28 | Fe-Cr | Selected soft-glass sealing |
| 4J29 / Kovar | Fe-Ni-Co | Selected hard-glass sealing |
| 4J42 / 4J45 | Fe-Ni | Selected glass sealing |
| 4J33 / 4J34 | Fe-Ni-Co | Alumina ceramic sealing |
This comparison is intended only as an initial material-selection guide.
The correct alloy should be selected according to the actual:
Glass or ceramic CTE
Sealing temperature
Operating temperature
Component geometry
Hermeticity requirements
Thermal cycling requirements
How to Select S4J38A Sealing Alloy
Before purchasing S4J38A, engineering and procurement teams should provide the following information.
1. Sealing Material
Provide the exact glass or ceramic grade.
2. CTE Requirement
Provide the required thermal expansion range and test temperature interval.
3. Sealing Temperature
Specify the actual processing temperature.
4. Operating Temperature
The service temperature may differ significantly from the sealing temperature.
5. Product Form
Specify whether you require:
Wire
Strip
Sheet
Rod
Tube
Foil
Custom components
6. Dimensions and Tolerance
Provide the drawing or detailed dimensions.
7. Hermeticity Requirement
Specify the required leak rate and testing method where applicable.
8. Certification
Specify whether you require:
Material certificate
Chemical analysis
CTE test report
Mechanical test report
Inspection report
EN 10204 3.1 documentation
S4J38A Material Specification
Because S4J38A may be supplied according to a manufacturer-specific or customer-specific specification, the purchasing document should clearly define:
Material designation
Chemical composition
CTE range
Temperature range
Product form
Dimensions
Tolerance
Heat-treatment condition
Surface condition
Testing requirements
Certification requirements
Do not rely on the alloy designation alone when purchasing precision sealing material.
For international procurement, a complete technical specification reduces the risk of receiving a materially different alloy under a similar commercial designation.
Important Note About S4J38A and 4J38
S4J38A should not automatically be considered equivalent to 4J38.
The standardized Chinese 4J38 designation is associated with a low-expansion, free-machining Fe-Ni-Se alloy, while the S4J38A product described on this page is identified as an Fe-Ni-Co-Cu controlled expansion sealing alloy.
If an equivalent standard grade is required, the equivalence should be confirmed through:
Chemical composition
CTE
Heat-treatment condition
Applicable standard
Material certificate
Customer specification
This distinction is important for engineering procurement and quality assurance.
Why Choose S4J38A from Greenergy Materials?
Hefei Ke Ningman New Energy Materials Technology Co., Ltd. focuses on the supply of special alloys and precision materials for industrial applications.
For S4J38A projects, we can support customers with:
Material specification review
Customized dimensions
Precision alloy sourcing
Wire and strip supply
Sheet and other product forms
CTE requirements
Chemical composition requirements
Material certification
Batch traceability
Export packaging
Technical communication
For new sealing projects, we recommend providing the glass or ceramic specification before material selection.
S4J38A Sealing Alloy FAQ
What is S4J38A sealing alloy?
S4J38A is a Fe-Ni-Co-Cu controlled expansion sealing alloy designation used for applications requiring controlled thermal expansion and metal-to-glass or metal-to-ceramic sealing.
What is S4J38A used for?
S4J38A can be evaluated for ceramic-to-metal sealing, glass-to-metal sealing, hermetic electronic packaging, semiconductor components, aerospace electronics and medical electronic applications.
Is S4J38A a controlled expansion alloy?
Yes. S4J38A is positioned as a controlled expansion sealing alloy, with material selection based on the required thermal expansion relationship between the metal and the sealing material.
Can S4J38A be used for ceramic-to-metal sealing?
Yes. S4J38A can be evaluated for ceramic-to-metal sealing when its thermal expansion characteristics are compatible with the selected ceramic and sealing process.
Can S4J38A be used for glass-to-metal sealing?
Yes. S4J38A can be considered for selected glass-to-metal sealing applications where the alloy and glass have suitable thermal expansion compatibility.
What is the CTE of S4J38A?
The required CTE should be specified according to the customer's temperature range and application. The certified CTE value should be confirmed using the applicable material specification and test report rather than relying on a single nominal value.
What is the chemical composition of S4J38A?
S4J38A is identified as an Fe-Ni-Co-Cu alloy on this product specification. Exact elemental ranges should be confirmed against the applicable S4J38A technical specification or material certificate.
Is S4J38A the same as 4J38?
Not necessarily. Standardized 4J38 is a different low-expansion Fe-Ni-Se alloy designation. S4J38A should only be treated as equivalent to another standard grade when chemical composition, CTE and applicable specifications have been formally verified.
Can S4J38A be supplied as strip?
S4J38A can be evaluated for strip supply according to the required thickness, width, tolerance and production requirements.
Can S4J38A be customized?
Yes. Product dimensions, material condition, surface requirements and inspection specifications can be discussed according to customer drawings and application requirements.
Can you provide a material certificate?
Material certificates and inspection documentation can be discussed according to the agreed specification and order requirements.
Request a Quote for S4J38A Sealing Alloy
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Required alloy designation
Glass or ceramic grade
Glass / ceramic CTE
Sealing temperature
Operating temperature
Product form
Thickness / diameter
Width / length
Dimensional tolerance
Quantity
Required inspection
Material certificate requirements
Our technical team can review your requirements and recommend the appropriate S4J38A Fe-Ni-Co-Cu controlled expansion sealing alloy specification.
Request a quotation for S4J38A sealing alloy today.